Nonlinear elastic constitutive relations of residually stressed composites with stiff curved fibres

Applied Mathematics and Mechanics - Mechanical models of residually stressed fibre-reinforced solids, which do not resist bending, have been developed in the literature. However, in some residually...     

Regular characters of classical groups over complete discrete valuation rings

Let $\mathfrak{o}$ be a complete discrete valuation ring with finite residue field $\mathsf{k}$ of odd characteristic, and let G be a symplectic or special orthogonal group scheme over $\mathfrak{o}$. For any $?\in \mathbb{N}$ let $G^{?}$ denote the ?-th principal congruence subgroup of $\mathbf{G}(\mathfrak{o})$. An irreducible character of the group $\mathbf{G}(\mathfrak{o})$ is said to be regular if it is trivial on a subgroup $G^{?+1}$ for some ?, and if its restriction to $G^{?}/G^{?+1}?\mathrm{Lie}(\mathbf{G})(\mathsf{k})$ consists of characters of minimal $\mathbf{G}({\mathsf{k}}^{\mathrm{alg}})$-stabilizer dimension. In the present paper we consider the regular characters of such classical groups over $\mathfrak{o}$, and construct and enumerate all regular characters of $\mathbf{G}(\mathfrak{o})$, when the characteristic of $\mathsf{k}$ is greater than two. As a result, we compute the regular part of their representation zeta function.     

Synthesis of α-fluoro-α,β-unsaturated esters monitored by 1D and 2D benchtop NMR spectroscopy

For optimization and control of pharmaceutically and industrially important reactions, chemical information is required in real time. Instrument size, handling, and operation costs are important criteria to be considered when choosing a suitable analytical method apart from sensitivity and resolution. This present study explores the use of a robust and compact nuclear magnetic resonance (NMR) spectrometer to monitor the stereo-selective formation of α-fluoro-α,β-unsaturated esters from α-fluoro-β-keto esters via deprotonation and deacylation in real time. These compounds are precursors of various pharmaceutically active substances. The real-time study revealed the deprotonation and deacylation steps of the reaction. The reaction was studied at temperatures ranging from 293 to 333 K by interleaved one-dimensional ¹H and ¹⁹F and two-dimensional ¹H–¹H COSY experiments. The kinetic rate constants were evaluated using a pseudo first-order kinetic model. The activation energies for the deprotonation and deacylation steps were determined to 28 ± 2 and 63.5 ± 8 kJ/mol, respectively. This showed that the deprotonation step is fast compared with the deacylation step and that the deacylation step determines the rate of the overall reaction. The reaction was repeated three times at 293 K to monitor the repeatability and stability of the system. The compact NMR spectrometer provided detailed information on the mechanism and kinetics of the reaction, which is essential for optimizing the synthetic routes for stepwise syntheses of pharmaceutically active substances.     

An Introduction to Influence Theory: Kinematics and Dynamics

Influence theory is a foundational theory of physics that is not based on traditional empirically defined concepts, such as positions in space and time, mass, energy, or momentum. Instead, the aim is to derive these concepts, and their empirically determined relationships, from a more primitive model. It is postulated that there exist things, which are call particles, that influence one another in a discrete and directed fashion resulting in a partially ordered set of influence events. The problem of consistent quantification of the influence events is considered. Observers are modeled as particle chains (observer chains) as if an observer were able to track a particle and quantify the influence events that the particle experiences. From these quantified influence events, consistent quantification of the universe of events based on the observer chains is studied. Herein, the kinematics and dynamics of particles from the perspective of influence theory are both reviewed and further developed.